[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate

Document Type

Article

Publication Date

1-1-2010

Abstract

The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]center dot 0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S, P donor set [S-Au-P angle = 178.01 (4)degrees]; a close intramolecular Au center dot center dot center dot O contact [ 2.964 (4) angstrom] also occurs. In the crystal structure, molecules are linked into supramolecular chains propagating along [010] by C-H center dot center dot center dot N, C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions. The solvent molecule is disordered about a twofold rotation axis.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

6

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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