[(Z)-O-Ethyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I): a monoclinic polymorph
Document Type
Article
Publication Date
1-1-2010
Abstract
The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P (1) over bar) polymorph [Hall et al. (1993). Aust. J. Chem. 46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.036 (2) angstrom]. In the crystal structure, molecules are arranged into supra-molecular chains along the b axis mediated by C-H center dot center dot center dot pi interactions.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
66
Issue
4
Publisher
International Union of Crystallography