[(Z)-Ethyl N-isopropylthiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

Document Type

Article

Publication Date

1-1-2010

Abstract

The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S, P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44 (5)degrees],with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.023 (4) angstrom]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

6

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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