Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine
Document Type
Article
Publication Date
8-15-2021
Abstract
Two new organic acid salts were synthesized, and their chemical structures were elucidated by various spectroscopy analyses including infra-red, one and two dimensions of nuclear magnetic resonance, and mass spectroscopy. The pH and thermal behavior and thermal stability displayed different acidity and stability which approved the existence of different chemical structures for two acid salts containing the same dication i.e., 4,4'-trimethylene-N,N'-dipiperidinium and two different anions of sulfate and hydrogensulfate. Although H-1 NMR did not show acid proton of HSO4](-), the FTIR spectra of acid salts act as key support to approve of their chemical structures. The thermal behavior and thermal stability of two as-synthesized acid salts were mainly different. This fact indicates various electrostatic and hydrogen-bonding interactions, which in turn, is further supports their proposed chemical structures. (C) 2021 Elsevier B.V. All rights reserved.
Keywords
Molten salt, Structure elucidation, Anion effect, Hydrogen bonding, Thermal behavior
Divisions
nanotechnology
Funders
Universiti Malaya, Malaysia (RU001-2020),Analytical and Testing Center of Nanotechnology & Catalysis Research Center (NANOCAT), the University of Malaya
Publication Title
Journal of Molecular Liquids
Volume
336
Publisher
Elsevier
Publisher Location
RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS