Inclusion controlled lanthanide-imidazolium functionalised carboxylate complexation

Document Type

Article

Publication Date

3-1-2012

Abstract

Imidazolium functionalized carboxylic acid forms a multi-component material with p-sulfonatocalix[4]arene and aquated lanthanide ions, stabilising dinuclear metal complexes for Y(3+) and Gd(3+). These have the simplest binding of two bridging carboxylates between the two metal centres (Y(3+)), or the same arrangement along with the simplest binding of one carboxylate bridging two metal ions for the larger metal ion (Gd(3+)).

Keywords

Chemistry

Divisions

CHEMISTRY

Publication Title

Dalton Transactions

Publisher

Royal Society of Chemistry

Additional Information

Chemistry Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur,Malaysia.

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