Bis(-5-hydroxy-2-{[2-(N-phenylthiocarbamoyl)hydrazin-1-ylidene]methyl} phenolato)bis[chloridozinc(II)] N,N-Dimethylformamide tetra-solvate

Authors

Kong Wai TanFollow
S.W. Ng
C.H. Ng
Mohd Jamil MaahFollow

Document Type

Article

Publication Date

1-1-2010

Abstract

In the dinuclear title compound, [Zn2(C14H 12N3O2S)2Cl2] ·4C3H7NO, the two monodeprotonated Schiff base ligands N,O,S:Ochelate to Zn atoms. The formally negatively charged O atom involved in chelation also serves as a bridge. The O, O′, N and S atoms comprise a square, and the Cl atom the apex of a square pyramid surrounding each metal atom. The solvate Dimethylformamide molecules, one of which is disordered over two positions in a 3:1 ratio, are hydrogen bonded to the dinuclear molecule. © 2010.

Keywords

Tetra

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

5

Publisher

International Union of Crystallography

Additional Information

Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA