{2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride

Authors

Kong Wai TanFollow
S.W. Ng
H.B. Shawish
Mohd Jamil MaahFollow

Document Type

Article

Publication Date

1-1-2010

Abstract

The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.

Keywords

Deprotonated Schiff base ligand, N, O, S-chelating, Phosphine-coordinated Ni, Square-planar geometry, The hydroxy group, Intramolecular O-H, Amino groups, Chloride anion, Hydrogen bonds

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Publisher

International Union of Crystallography

Additional Information

Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA