Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate]

Document Type

Article

Publication Date

1-1-2010

Abstract

In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]center dot C2H6O}(n), the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The mu(3)-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O-H center dot center dot center dot O hydrogen bonds.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

3

Publisher

International Union of Crystallography

Publisher Location

2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND

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