Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate]

Authors

• O. Sadeghi
• M.M. Amini
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]center dot C2H6O}(n), the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The mu(3)-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O-H center dot center dot center dot O hydrogen bonds.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Sadeghi, O.; Amini, M.M.; and Ng, S.W., "Poly[[(mu(3)-isonicotinato-kappa O-3:O:N)(triphenylphosphine-kappa P)silver(I)] ethanol solvate]" (2010). Research Publications (2006 to 2010). 3904.
https://knova.um.edu.my/research_publications_2006_2010/3904

Volume

66

Issue

3

Publisher

International Union of Crystallography

Publisher Location

2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND