Poly[(mu(3)-4-carboxypyridine-3-carboxylato-kappa N-3:O-3:O-4)(triphenylphosphine-kappa P)silver(I)]

Authors

• O. Sadeghi
• M.M. Amini
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

In the title 1:1 silver(I) 4-carboxypyridine-3-carboxylate adduct with triphenylphosphine, [Ag(C7H4NO4)(C18H15P)](n), the carboxylate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag atom exists in a distorted tetrahedral geometry. The H atom of the carboxylate is midway between two O atoms of the two carboxyl groups, thus forming a strong intramolecular hydrogen bond.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Sadeghi, O.; Amini, M.M.; and Ng, S.W., "Poly[(mu(3)-4-carboxypyridine-3-carboxylato-kappa N-3:O-3:O-4)(triphenylphosphine-kappa P)silver(I)]" (2010). Research Publications (2006 to 2010). 3903.
https://knova.um.edu.my/research_publications_2006_2010/3903

Volume

66

Issue

9

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA