Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)]

Authors

• C.T. Keng
• K.M. Lo
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

Two nicotinate binding modes are observed in the dinuclear title compound, [Sn-2(C7H6Br)(4)(C6H4NO2)(4)(H2O)(2)]: in the first, a terminal O,O'-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds to two cations. The two Sn atoms exist in trans-C2SnNO4 pentagonal-bipyramidal geometries. Adjacent dinuclear units are linked by O-H...N hydrogen bonds, generating a linear chain, which propagates in the b-axis direction. O-H...O interactions are also observed.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Keng, C.T.; Lo, K.M.; and Ng, S.W., "Di-mu-nicotinato-kappa N-2/O;kappa O-2/N-bis[aquabis(4-bromobenzyl)(nicotinato-kappa O-2,O `)tin(IV)]" (2010). Research Publications (2006 to 2010). 3369.
https://knova.um.edu.my/research_publications_2006_2010/3369

Volume

66

Issue

8

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA