catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `]

Authors

• T.C. Keng
• K.M. Lo
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

The Sn atom in the title polymeric compound, [Sn(C7H7)(3)-(C8H12NO2S2)](n), exists in a trans-C3O2 trigonal-bipyramidal coordination environment in the two independent formula units. The carboxylate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O-covalent bond by 0.093 (4) angstrom and in the second molecule, the Sn atom is displaced by 0.105 (4) angstrom in the same direction.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Keng, T.C.; Lo, K.M.; and Ng, S.W., "catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `]" (2010). Research Publications (2006 to 2010). 3219.
https://knova.um.edu.my/research_publications_2006_2010/3219

Volume

66

Issue

10

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA