{2-[(2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl]-6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
Document Type
Article
Publication Date
1-1-2010
Abstract
The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
66
Issue
9
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA
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