(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-kappa N-2(1),S]methyl}phenolato-kappa O-1)(triphenylphosphane-kappa P)nickel(II) chloride
Document Type
Article
Publication Date
1-1-2010
Abstract
The deprotonated Schiff base ligand in the title salt, [Ni(C9H10N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
Recommended Citation
Shawish, H.B.; Maah, Mohd Jamil; and Ng, S.W., "(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-kappa N-2(1),S]methyl}phenolato-kappa O-1)(triphenylphosphane-kappa P)nickel(II) chloride" (2010). Research Publications (2006 to 2010). 2788.
https://knova.um.edu.my/research_publications_2006_2010/2788
Volume
66
Issue
11
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA