Bis 1,3-dihydroxy-2-hydroxymethyl-2-(2-oxidobenzylideneamino)propane-kap pa N-3,O,O ' nickel(II) pyridine solvate

Document Type

Article

Publication Date

1-1-2006

Abstract

The Ni-II atom in the title complex, [Ni(C11H14NO4)(2)]center dot C5H5N, is chelated by a terdentate Schiff base anion in a slightly disotorted octahedral geometry. One of the two coordinated hydroxyl groups forms a hydrogen bond to the pyridine solvent while other hydroxyl groups are engaged in intermolecular hydrogen bonding, forming a two-dimensional layer.

Keywords

Crystal-Structure, Schiff-Bases, Complexes, Reactivity, Ni(Ii)

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

62

Publisher

International Union of Crystallography

Additional Information

Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA

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