Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate

Document Type

Article

Publication Date

1-1-2009

Abstract

The metal atom in the title compound, [Cd(C15H13N2O4)2]·2C2H6OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the -NH- unit, and O-H...O hydrogen bonds link molecules into a supramolecular chain.

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

65

Issue

5

Additional Information

Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA

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