S-[4-(Trimethylammonio)phenyl] thiosulfate, an aromatic organic thiosulfate

Document Type

Article

Publication Date

1-1-2004

Abstract

The title compound, C9H13NO3S2, exists as a zwitterion with crystallographic mirror symmetry. The central S atom of the S2O3 group adopts a slightly distorted tetrahedral coordination geometry. The S-S bond length is 2.1137 (7) Å, while the S-O bond lengths are in the range 1.4417 (12)-1.457 (2) Å. The zwitterions in the crystal adopt a head-to-tail arrangement, which leads to the formation of a three-dimensional network through C-H ⋯ O hydrogen bonds.

Keywords

Bond lengths, Head-to-tail arrangement, Tetrahedral coordination geometry, Zwitterionic compounds, Ammonium compounds, Crystal symmetry, Crystallography, X-Ray Ethers, Hydrogen bonds, Methanol, Positive ions, Thermal effects, Aromatic compounds

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section C: Crystal Structure Communications

Volume

60

Issue

8

Additional Information

Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA

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