Ecofriendly zinc oxide-decorated poly-3-hydroxyalkanoate-graft-poly-methyl acrylate copolymer film for photocatalysis-mediated water treatment

Document Type

Article

Publication Date

4-1-2022

Abstract

The application of microbiologically produced polymer, i.e., medium-chain-length poly-3-hydroxyalkanoate (mcl-PHA), in environmental remediation technology was investigated. Mcl-PHA and its graft copolymer, polyhydroxyalkanoate-g-polymethylacrylate (PHA-g-PMA), were used as the supporting matrices to hold zinc oxide microparticles (ZnO MPs). The polymer composites, i.e., neat PHA/ZnO and PHA-g-PMA/ZnO, were tested as the catalytic support materials to enhance photodegradation of an organic dye, i.e., methylene blue (MB). PHA-g-PMA/ZnO film composite yields a significant MB photodegradation compared to the neat PHA/ZnO composite. Photodegradation performance was investigated as MB removal percentage (%) and rate constant of photocatalysis reaction (k). The enhanced photocatalytic performance in PHA-g-PMA is discussed.

Keywords

Biological polymer, Poly-3-hydroxyalkanoate (PHA), Graft copolymer, Photocatalysis, Water remediation

Divisions

InstituteofBiologicalSciences,deputyresearch

Funders

Ministry of Higher Education, Malaysia (MOHE) [Grant No; FP038-2020],Universiti Malaya,Institut Pengurusan dan Pemantauan Penyelidikan, Universiti Malaya [Grant No; IIRG017A-2019, UM.C/625/1/HIR/MOHE/05]

Publication Title

Journal of Polymers and the Environment

Volume

30

Issue

4

Publisher

Springer

Publisher Location

ONE NEW YORK PLAZA, SUITE 4600, NEW YORK, NY, UNITED STATES

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