An investigation into the PVA:MC:NH4Cl-Based Proton-Conducting Polymer-Blend Electrolytes for Electrochemical Double Layer Capacitor (EDLC) device application: The FTIR, circuit Design and electrochemical studies
Document Type
Article
Publication Date
2-1-2022
Abstract
In this report, the preparation of solid polymer electrolytes (SPEs) is performed from polyvinyl alcohol, methyl cellulose (PVA-MC), and ammonium chloride (NH4Cl) using solution casting methodology for its use in electrical double layer capacitors (EDLCs). The characterizations of the prepared electrolyte are conducted using a variety of techniques, including Fourier transform infrared spectroscopy (FTIR), electrical impedance spectroscopy (EIS), cyclic voltammetry (CV), and linear sweep voltammetry (LSV). The interaction between the polymers and NH4Cl salt are assured via FTIR. EIS confirms the possibility of obtaining a reasonably high conductance of the electrolyte of 1.99 x 10(-3) S/cm at room temperature. The dielectric response technique is applied to determine the extent of the ion dissociation of the NH4Cl in the PVA-MC-NH4Cl systems. The appearance of a peak in the imaginary part of the modulus study recognizes the contribution of chain dynamics and ion mobility. Transference number measurement (TNM) is specified and is found to be (t(ion)) = 0.933 for the uppermost conducting sample. This verifies that ions are the predominant charge carriers. From the LSV study, 1.4 V are recorded for the relatively high-conducting sample. The CV curve response is far from the rectangular shape. The maximum specific capacitance of 20.6 F/g is recorded at 10 mV/s.
Keywords
Polymer blending, Ammonium salt, FTIR, EIS, Circuit design, TNM, LSV, CV
Divisions
foundation
Funders
University of Sulaimani,Prince Sultan University,Komar University of Science and Technology,Princes Nourah bint Abdulrahman University, Riyadh, Saudi Arabia [Grant No: PNURSP2022R58]
Publication Title
Molecules
Volume
27
Issue
3
Publisher
MDPI
Publisher Location
ST ALBAN-ANLAGE 66, CH-4052 BASEL, SWITZERLAND