Hybrid carboxymethyl kappa-carrageenan/carboxymethyl cellulose- based biopolymer electrolytes for dye-sensitized solar cell application
Document Type
Article
Publication Date
1-1-2022
Abstract
Natural biopolymers have recently attracted a lot of attention for the development of new polymer electrolytes due to their environmental friendliness, nontoxicity, and abundance in nature. Biopolymer electrolytes based on carboxymethyl kappa-carrageenan/carboxymethyl cellulose incorporated with sodium iodide were prepared and their structural and electrochemical stability were investigated using electrochemical impedance spectroscopy, Fourier transform infrared spectroscopy, transference number measurement, and linear sweep voltammetry. The film containing 30 wt% sodium iodide had the highest ionic conductivity and the highest relative number of charge carriers at room temperature. The relative number of charge carriers for each prepared electrolyte film in this study increased with salt concentration, according to Barker's electrolyte dissociation theory. The highest conducting electrolyte and the lowest salt concentration electrolyte films were used to fabricate and characterise dye-sensitized solar cell (DSSC). These DSSCs responded well to a light intensity of 100 mW cm(-2).
Keywords
Polymer blend, Electrolytes, Carboxymethyl kappa-carrageenan, Carboxymethyl cellulose, Sodium iodide
Divisions
foundation
Funders
Universiti Teknologi MARA, Fundamental Research Grant Scheme (FRGS) [Grant No: 600-IRMI/FRGS 5/3 (342/2019)],Ministry of Higher of Higher Education (MOHE)
Publication Title
International Journal of Electrochemical Science
Volume
17
Issue
1
Publisher
Electrochemical Science Group
Publisher Location
BORIVOJA STEVANOVICA 25-7, BELGRADE, 11000, SERBIA