Naphthalocyanine-based NIR organic photodiode: Understanding the role of different types of fullerenes

Document Type

Article

Publication Date

11-1-2021

Abstract

In this work, we presented experimental observation on solution-processed bulk heterojunction organic photodiode using vanadyl 2,11,20,29-tetra tert-butyl 2,3 naphthalocyanine (VTTBNc) as a p-type material. VTTBNc is blended with two different acceptors, which are PC61BM and PC71BM, to offer further understanding in evaluating the performance in organic photodiode (OPD). The blend film of VTTBNc:PC71BM with a volumetric ratio of 1:1 exhibits optimized performance in the VTTBNc blend structure with 2.31 x 10(9) Jones detectivity and 26.11 mA/W responsivity at a -1 V bias. The response and recovery time of VTTBNc:PC71BM were recorded as 241 ms and 310 ms, respectively. The light absorption measurement demonstrated that VTTBNc could extend the light absorption to the near-infrared (NIR) region. The detail of the enhancement of the performance by adding VTTBNc to the blend was further explained in the discussion section.

Keywords

Organic photodiode, NIR, Naphthalocyanine, Fullerene, Solution-processed

Divisions

Science

Funders

Universiti Malaya,Ministry of Education, Malaysia[ST025-2020],Ministry of Education, Malaysia[GPF080B-2020]

Publication Title

Micromachines

Volume

12

Issue

11

Publisher

MDPI

Publisher Location

ST ALBAN-ANLAGE 66, CH-4052 BASEL, SWITZERLAND

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