Multiple effect of thermal treatment approach on PVDF membranes: Permeability enhancement and silver nanoparticles immobilization
Document Type
Article
Publication Date
8-1-2021
Abstract
Impregnation of the noble metal, silver nanoparticles (AgNPs) as a disinfectant into the polymeric membrane is one of the empirical modification methods in producing safe drinking water. However, the dispersion and immobilization of AgNPs during membrane fabrication and application is least discussed despite numerous leaching phenomena reported. In this study, silver nanoparticles type 1 (AgNPs-1) and type 2 (AgNPs-2) were prepared and incorporated into polyvinylidene fluoride (PVDF) ultrafiltration membrane with the presence of thermal treatment. The effect of thermal treatment was studied at temperature 25 degrees C, 40 degrees C and 55 degrees C which significantly influenced the physicochemical characteristics of the PVDF membrane. Membrane incorporated with AgNPs-1 and AgNPs-2 fabricated at highest temperature portrayed improved mechanical properties and pure water flux. PVDF/PVP/AgNPs-2 membrane released the smallest amount of Ag (3.81%) while PVDF/PVP/ AgNPs-1 cast at 40 degrees C released the largest amount of Ag (42.34%) during the phase inversion at fabrication. Notably, no Ag leaching was found in all membranes during the dead-end filtration at 0.5 bar. Membranes with AgNPs-1 and AgNPs-2 showed remarkable bactericidal performance towards E. coli with a percentage reduction of 90.38% and 80.77%, respectively. Thus, membranes with AgNPs fabricated at 55 degrees C offered better mechanical properties of the enhanced permeability and excellent stability of AgNPs immobilization which signified the thermal treatment approach.
Keywords
Silver nanoparticles immobilization, Polymeric membrane, Thermal treatment phase inversion
Divisions
sch_che,nanotechnology
Funders
University of Malaya Research Grant (RP034D-15AET),Ministry of Education, Malaysia (FP040-2018A)
Publication Title
Journal of Environmental Chemical Engineering
Volume
9
Issue
4
Publisher
Elsevier Science Ltd
Publisher Location
THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND