Plasmon-enhanced visible photodetectors based on hexagonal boron nitride (hBN) with gold (Au), silver (Ag), and non-alloyed bimetallic (Au/Ag) nanoparticles

Document Type

Article

Publication Date

1-1-2025

Abstract

Two-dimensional (2D) hexagonal boron nitride (hBN) has garnered significant attention due to its exceptional thermal and chemical stability, excellent dielectric properties, and unique optical characteristics, making it widely used in deep ultraviolet (DUV) applications. However, the integration of hBN with plasmonic materials in the visible region (532 nm) has not been fully explored, particularly in terms of morphology regulation and size control of mono- and bimetallic nanoparticles (BMNPs) namely gold (Au), silver (Ag) and Au-Ag. A Schottky junction-based metal-semiconductor contact configuration is employed to achieve hot-carrier reflections on the metal side, enhancing the quantum efficiency of the photodetector. The fabricated metallic NPs/hBN photodetector demonstrates a responsivity of 1.33 A/W, a specific detectivity of 1.03 x 1011 Jones, an ultra-low dark current of 7.00 mu A and a high photo response ratio of 2.47. This improved performance is attributed to the visible light-modulated band-to-band excitation in hBN layer and internal photoemission resulting from the NPs/hBN junction. The device also exhibits a rapid response speed of less than 300 mu s for all the devices. This approach of integrating 2D/metal opens possibilities for fabricating low-cost, high-performance, flexible photodetectors for a range of optoelectronic devices.

Keywords

Hexagonal boron nitride (hBN), Plasmonic enhancement, Metallic nanoparticles, Visible light photodetector, External quantum efficiency (EQE)

Divisions

photonics

Funders

Institut Pengurusan dan Pemantauan Penyelidikan, Universiti Malaya (2/2024),Universiti Malaya Research Excellence (GPF018A-2023),Research University Geran (Faculty Programme)

Publication Title

Scientific Reports

Volume

15

Issue

1

Publisher

Nature Research

Publisher Location

HEIDELBERGER PLATZ 3, BERLIN, 14197, GERMANY

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