Deuterated Multiple-Resonance Thermally Activated Delayed Fluorescence Emitter and Their Application in Vacuum-Deposited Organic Light-Emitting Diodes
Document Type
Article
Publication Date
10-1-2024
Abstract
Multiple-resonance thermally activated delayed fluorescence (MR-TADF) emitters have garnered significant attention in recent years due to their remarkable properties, such as high luminescent quantum yield, robustness, and their compliance with the Broadcast Television 2020 standard for the new generation of ultrahigh-definition. Despite these advancements, the operational lifetimes of organic light-emitting diodes (OLEDs) relying on MR-TADF emitters still fall short for practical application. It is believed that the enhancement of the intrinsic molecular stability of tBu-DABNA, a fundamental backbone of MR-TADF emitters, holds great promise to be a universal strategy for all MR-TADF emitters improving the operational lifetimes of OLEDs. Herein, the design and synthesis of targeted deuteration are reported on donor and/or backbone of MR-TADF emitters, where the structure-property relationship between intrinsic molecular stability upon isotopic effect and device operational stability are examined. The isotopic analogs show a gradual increase in the device operational stability and achieve long-lifetime LT80 (80% of the initial luminance of 1000 cd m-2) of 24.3 h for TADF-sensitized fluorescence OLED, representing a sevenfold enhancement when compared with the undeuterated counterpart. This strategic deuteration approach underlines the importance of structural modification on materials toward device operational stability. Recent research has focused on enhancing the operational lifetimes of organic light-emitting diodes (OLEDs) utilizing multiple-resonance thermally activated delayed fluorescence (MR-TADF) emitters. By strategically deuterating the fundamental backbone (NBN) of MR-TADF emitters, a sevenfold increase in device operational stability is achieved, demonstrating the significance of the deuterated effect for improving OLED performance. image
Keywords
deuteration, electroluminescence, multiple-resonance TADF, operational lifetime, organic light-emitting diode
Divisions
CHEMISTRY
Funders
National Natural Science Foundation of China (NSFC) (22275114),Science and Technology Planning Project of Shenzhen Municipality (WDZC20220817160017003),Cross-Disciplinary Research Fund of Tsinghua Shenzhen International Graduate School (SIGS), Tsinghua University (JC2022003),Overseas Research Cooperation Fund Research Plan of Tsinghua SIGS (HW2023006),Scientific Research Startup Fund of SIGS, Tsinghua University (QD2021027C) ; (QD2023001C)
Publication Title
Advanced Optical Materials
Volume
12
Issue
30
Publisher
Wiley
Publisher Location
POSTFACH 101161, 69451 WEINHEIM, GERMANY