Switching thermally activated delayed fluorescence to room temperature phosphorescence for oxygen sensing: Effect of donor substituents of trifluoromethylphenyl
Document Type
Article
Publication Date
2-5-2024
Abstract
Two compounds consisting of electron-accepting trifluoromethylphenyl moiety and electron-donating phenoxazine and phenothiazine moieties were designed and synthesized via Buchwald-Hartwig coupling reaction. Thermal, photophysical, and electrochemical properties of the compounds are discussed. Only compound with phenothiazine form molecular glass, with glass transition temperatures of 90 degrees C. The geometry and electronic characteristics of the compounds were substantiated within density functional theory (DFT). 10,10 `-(2-(Trifluoromethyl)-1,4-phenylene)bis(10H-phenoxazine) shows efficient thermally activated delayed fluorescence with high spin-orbit coupling values. 10,10 `-(2-(Trifluoromethyl)-1,4-phenylene)bis(10H-phenothiazine) as efficient room-temperature phosphor shows high oxygen sensitivity.
Keywords
Dual emission, Room temperature phosphorescence, Phenothiazine, Phenoxazine, Trifluoromethylphenyl
Divisions
CHEMISTRY,PHYSICS
Funders
Research Council of Lithuania (LMTLT) [S-MIP-22-78]
Publication Title
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Volume
306
Publisher
Elsevier
Publisher Location
THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND