Multi-wall carbon nanotubes tailored eutectic composites for solar energy harvesting

Document Type

Article

Publication Date

2-1-2024

Abstract

Carbonaceous thermal energy storage involving PCMs has gained an increasing research interest owing to their higher thermal conductivity and energy storage density. The current work analyses the thermophysical properties of a nano-enhanced eutectic phase change material (NeUPCM) laden with different concentrations (ranges from 0 wt% - 0.7 wt%) of multi-wall carbon nanotube (MWCNT). Paraffin wax-palmitic acid (PW-PA) binary eutectic was produced initially by facile melt blending, and then MWCNTs were doped via standard two-step nanocomposite synthesis protocol. Nanocomposites showed a slower decomposition rate, and the thermal resistance index improved. MWCNT enhance the thermal conductivity of the eutectic base (140 %), which reaches a maximum value of 0.619 W/(m & sdot;K) for 0.5 wt% loadings, and the maximum increment of 13.2 % of latent heat was noted for 0.7 wt% loading of MWCNT (which is having a melting temperature of 53 degrees C). The sample doped with 0.5 wt% MWCNT(C3) showed the highest thermal effusivity. The NeUPCMs also displayed improved photothermal performance and solar absorptivity. Corrosion analysis against copper revealed that the composite is suitable for long-term usage. The NeUPCMs maintained good reliability even after 500 melt-freeze cycles. In short, the proposed NeUPCMs hold significant potential to be employed for thermal energy storage purposes.

Keywords

Thermal effusivity, Thermal cycling, Photothermal conversion, Thermal energy storage, Corrosion analysis

Divisions

umpedac

Funders

UM Power Energy Dedicated Advanced Centre (UMPEDAC) , Japan International Cooper- ation Agency [IF005-2021],UM Power Energy Dedicated Advanced Centre (UMPEDAC) , Japan International Cooper- ation Agency [IF034-2022],UM Power Energy Dedicated Advanced Centre (UMPEDAC) , Japan International Cooper- ation Agency [MG009-2023],Higher Institution Centre of Excellence (HICoE) Program Research Grant,UMPEDAC-2020 (MOHE HICOE-UMPEDAC),UM Power Energy Dedicated Advanced Centre (UMPEDAC),Japan International Cooperation Agency for AUN/SEED-Net on Collaboration Education Program [PUM CE1901],Japan ASEAN Collaborative Education Program (JACEP) [IF005-2021],Japan ASEAN Collaborative Education Program (JACEP) [IF034-2022],Smart Building Energy Management System Suitable for Tropical Climate Countries [MG009-2023],Ministry of Education Malaysia and University of Malaya,Sunway University via Sunway University

Publication Title

Energy

Volume

288

Publisher

Elsevier

Publisher Location

THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

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