Organic-inorganic composite nanocoatings with superhydrophobicity and thermal stability

Document Type

Article

Publication Date

1-1-2024

Abstract

Purpose: This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles. Design/methodology/approach: Sol-gel methods have been used to design superhydrophobic glass substrates through surface modification by using low-surface-energy Isooctyl trimethoxysilane (ITMS) and Ethyl trimethoxysilane (ETMS) solution. Hierarchical double-rough scale solid surface was built by Si micro- and nanoparticles to enhance the surface roughness. The prepared sol was applied onto glass substrate using dip-coating method and was dried at control temperature of 400°C inside the tube furnace. Findings: The glass substrate achieved the water contact angle as high as 154 ± 2° and 150.4 ± 2° for Si/ITMS and Si/ETMS films, respectively. The Si/ITMS and Si/ETMS also were equipped with low sliding angle as low as 3° and 5°, respectively. The Si micro- and nanoparticles in the coating system have created nanopillars between them, which will suspend the water droplets. Both superhydrophobic coatings have showed good stability against high temperature up to 200°C as there are no changes in WCA shown by both coatings. Si/ITMS film sustains its superhydrophobicity after impacting with further temperature up to 400°C and turns hydrophobic state at 450°C. Research limitations/implications: Findings will be useful to develop superhydrophobic coatings with high thermal stability. Practical implications: Sol method provides a suitable medium for the combination of organic-inorganic network to achieve high hydrophobicity with optimum surface roughness. Originality/value: Application of different alkyl chain groups of silane resin blending with micro- and nanoparticles of Si pigments develops superhydrophobic coatings with high thermal stability. © 2018, Emerald Publishing Limited.

Keywords

Coatings, Hierarchical roughness, Organic coatings, Superhydrophobic, Thermal stability

Publication Title

Pigment and Resin Technology

Divisions

umpedac

Funders

Higher Institution Centre of Excellence,MOHE HICOE,UM Power Energy Dedicated Advanced Centre

Volume

53

Issue

1

Publisher

Emerald Publishing

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