Plasmonic gold nanoparticles coated TiO2 photoanode for efficiency enhancement in dye-sensitized solar cells (DSSCs)

Document Type

Article

Publication Date

10-1-2023

Abstract

In this work, gold nanoparticles (NPs) of 100 nm in size were added to the active layer of DSSC. The electrolyte is a gel polymer electrolyte (GPE) containing PEO, PhCh, TPAI, BMII, I-2, DMF, EC, TBP, and GuSCN. The DSSCs have been characterized via J-V characteristics, IMVS, and IMPS measurements. On illumination at AM 1.5, the cell with 3 wt.% Au NP in the photoanode exhibits an eta of 8.56% with J(sc) of 19.82 mA cm(-2), V-oc of 0.72 V and FF of 60%. The same cell also exhibited the lowest tau(tr) of 7.32 ms and longest tau(rec) of 115.33 ms.

Keywords

Charge recombination effect, DSSC, gold nanoparticles, guanidinium thiocyanate (GuSCN), photoanodes, tetra propyl ammonium iodide (TPAI), titanium dioxide (TiO2)

Divisions

PHYSICS

Funders

UM Grant FRG (FG029-17AFR)

Publication Title

Molecular Crystals and Liquid Crystals

Volume

764

Issue

1

Publisher

Taylor & Francis

Publisher Location

2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND

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