Towards sustainable green diesel fuel production: Advancements and opportunities in acid-base catalyzed H2-free deoxygenation process

Document Type

Article

Publication Date

9-1-2023

Abstract

This review delves into the potential of renewable biomass for green diesel production. Deoxygenation technology offers a promising method for converting biomass-derived oxygenates oil into high-grade hydrocarbon factions. Hence, various deoxygenation pathways of biomass conversion under free-hydrogen environment were explored. Additionally, the prospects of acid-base bifunctional catalysts to facilitate deoxygenation was discussed, highlighting the correlation between the physicochemical properties of the catalysts and catalytic activity. However, it should be noted that the acid-base characteristics of the catalysts contribute to the breaking of C-O bonds of oxygenated oil via undesirable pathways, which contributed to unfavorable by-product and catalyst deactivation.

Keywords

Deoxygenation, Decarboxylation, decarbonylation, Green diesel, Renewable diesel, Active metals-mesoporous support, Catalyst deactivation

Publication Title

Catalysis Communications

Divisions

nanotechnology

Funders

Universiti Malaya, Malaysia (MOHE-Top 100 (IIRG)-IISS (IIRG002A-2020IISS)),SATU Joint Research Scheme RU Grants (ST0262021)

Volume

182

Publisher

Elsevier

Publisher Location

RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS

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