Electrocatalytic and structural properties and computational calculation of PAN-EC-PC-TPAI-I-2 gel polymer electrolytes for dye sensitized solar cell application
Document Type
Article
Publication Date
7-8-2021
Abstract
In this study, gel polymer electrolytes (GPEs) were prepared using polyacrylonitrile (PAN) polymer, ethylene carbonate (EC), propylene carbonate (PC) plasticizers and different compositions of tetrapropylammonium iodide (TPAI) salt. Linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) measurements were done using non-blocking Pt-electrode symmetric cells. The limiting current (J(lim)), apparent diffusion coefficient of triiodide ions and exchange current were found to be 12.76 mA cm(-2), 23.41 x 10(-7) cm(2) s(-1) and 11.22-14.24 mA cm(-2), respectively, for the GPE containing 30% TPAI. These values are the highest among the GPEs with different TPAI contents. To determine the ionic conductivity, the EIS technique was employed with blocking electrodes. The GPE containing 30% TPAI exhibited the lowest bulk impedance, R-b (22 Omega), highest ionic conductivity (3.62 x 10(-3) S cm(-1)) and lowest activation energy. Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD) techniques were utilized for structural characterization. Functional group interactions among PAN, EC, PC and TPAI were studied in the FTIR spectra of the GPEs. An up-shift of the XRD peak indicates the polymer-salt interaction and possible complexation of the cation (TPA(+) ion) with the lone pair of electrons containing site -C-N at the N atom in the host polymer matrix. On the other hand, computational study shows that TPAI-PAN based GPE possesses the lowest frontier orbital bandgap, which coincided with the enhanced electrochemical and electrocatalytic performance of GPE. The dye-sensitized solar cell (DSSC) fabricated with these GPEs showed that the J(SC) (19.75 mA cm(-2)) and V-OC (553.8 mV) were the highest among the GPEs and hence the highest efficiency, eta (4.76%), was obtained for the same electrolytes.
Keywords
Improved performance, Counter-electrode, Spectroscopic characterization, Polyacrylonitrile pan, Electrical-properties, Ion conduction, X-ray, Carbon, Iodide, Stabilization
Divisions
fac_eng,PHYSICS,nanocat
Funders
University Grants Commission, India, People's Republic of Bangladesh
Publication Title
RSC Advances
Volume
11
Issue
37
Publisher
Royal Society of Chemistry
Publisher Location
THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND