Functionalized graphene quantum dots for dye-sensitized solar cell: Key challenges, recent developments and future prospects

Document Type

Article

Publication Date

7-1-2021

Abstract

One of the pioneering materials nowadays is graphene quantum dot (GQD), which possesses outstanding electrical, thermal, and mechanical properties followed by less toxicity and robust photoluminescence. These commendable properties allow GQD to be suitable enough to apply in dye-sensitized solar cells, incapacitating current material limits. Nevertheless, pure GQDs have many challenges in reaching their full potential in DSSC. Chemical modification and functionalization tune the physical and chemical properties, driving GQD towards high-performance DSSC. This is an ideal way of modifying GQD because the chemical adsorption of atoms or molecules prevents the destruction of the carbon network without substitutional impurities. Here, we deliver a short outline of progress in understanding GQD functionalization from theoretical/computational perspectives. This chemically modified GQD is then linked with the performance of DSSC. The review also summarizes the electron transport in GQD-DSSC to minimize back-electron transmission recombination at the photoelectrode/ electrolyte edge. The impact, outlook, and future prospects of the GQD-DSSC are included as a conclusion in this review.

Keywords

Dye-sensitized solar cells, Electron transport, Functionalization, Graphene quantum dots

Divisions

umpedac

Funders

Ministry of Higher Education Malaysia (MoHE) under Universitas Pertamina-Uniten International Collaboration [2020001YCUPU],Universiti Tenaga Nasional (UNITEN) under the Fundamental Research Grant Scheme (FRGS) [FRGS/1/2019/STG07/UNITEN/02/3],Universiti Tenaga Nasional (UNITEN) under UNITEN BOLD [RJO10517844/070],Universiti Tenaga Nasional (UNITEN) under Telkom University-Uniten International Collaboration [2020101TELCO],Universiti Tenaga Nasional (UNITEN) under Universitas Pertamina-Uniten International Collaboration [2020001YCUPU]

Publication Title

Renewable and Sustainable Energy Reviews

Volume

144

Publisher

Pergamon-Elsevier Science Ltd

Publisher Location

THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

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