Bio-based Poly(hydroxy urethane)s: Synthesis and pre/post-functionalization
Document Type
Article
Publication Date
6-1-2021
Abstract
New and emerging demand for polyurethane (PU) continues to rise over the years. The harmful isocyanate binding agents and their integrated PU products are at the height of environmental concerns, in particular PU (macro and micro) pollution and their degradation problems. Non-isocyanate poly(hydroxy urethane)s (NIPUs) are sustainable and green alternatives to conventional PUs. Since the introduction of NIPU in 1957, the market value of NIPU and its hybridized materials has increased exponentially in 2019 and is expected to continue to rise in the coming years. The secondary hydroxyl groups of these NIPU ` s urethane moiety have revolutionized them by allowing for adequate pre/post functionalization. This minireview highlights different strategies and advances in pre/post-functionalization used in biobased NIPU. We have performed a comprehensive evaluation of the development of new ideas in this field to achieve more efficient synthetic biobased hybridized NIPU processes through selective and kinetic understanding.
Keywords
Bio-based cyclic carbonate, Polyhydroxyurethane, Nanophase interaction, Pre, Post-functionalization, Hybrid precursor nanoparticle
Divisions
fac_eng,Science
Funders
Ministry of Education of Malaysia (PRGS:PR006-2019A),Universiti Malaya (ST007-2019) (GPF002A-2019A)
Publication Title
Chemistry - An Asian Journal
Volume
16
Issue
11
Publisher
Wiley-V C H Verlag GMBH
Publisher Location
POSTFACH 101161, 69451 WEINHEIM, GERMANY