Two New isoquinoline alkaloids from the bark of Alphonsea cylindrica King and their antioxidant activity

Document Type

Article

Publication Date

1-1-2019

Abstract

Two new isoquinoline alkaloids, iraqiine (1) and kareemine (2), along with five known alkaloids, muniranine (3), kinabaline (4), O-methylmoschatoline (5), atherospermidine (6) and N-methylouregidione (7), were purified from the dichloromethane crude extract of Alphonsea cylindrica bark. The structures of these compounds were elucidated through extensive 1D and 2D NMR, IR and LC–MS studies and comparison with previously reported data. Compounds (1–5 and 7) were tested for their antioxidant activity using in vitro DPPH radical scavenging assay, and 1, 3 and 4 showed the highest antioxidant activities with IC50 values of 48.77 ± 1.01, 44.51 ± 1.12 and 64.28 ± 0.93 μg/ml, respectively.

Keywords

Alphonsea cylindrical, Isoquinoline, Oxoaporphine, Bisbenzylisoquinoline, DPPH

Divisions

CHEMISTRY

Funders

Universiti Pendidikan Sultan Idris Special Grant Scheme (Fundamental) 2017-0331-101-01

Publication Title

Phytochemistry Letters

Volume

29

Publisher

Elsevier

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