Electrolyte selection for supercapacitive devices: a critical review
Document Type
Article
Publication Date
1-1-2019
Abstract
Electrolytes are one of the vital constituents of electrochemical energy storage devices and their physical and chemical properties play an important role in these devices' performance, including capacity, power density, rate performance, cyclability and safety. This article reviews the current state of understanding of the electrode-electrolyte interaction in supercapacitors and battery-supercapacitor hybrid devices. The article discusses factors that affect the overall performance of the devices such as the ionic conductivity, mobility, diffusion coefficient, radius of bare and hydrated spheres, ion solvation, viscosity, dielectric constant, electrochemical stability, thermal stability and dispersion interaction. The requirements needed to design better electrolytes and the challenges that still need to be addressed for building better supercapacitive devices for the competitive energy storage market have also been highlighted. © 2019 The Royal Society of Chemistry.
Keywords
Capacitance, Carbonization, Aqueous electrolyte
Divisions
PHYSICS
Funders
Flagship Strategic Leap 3 (RDU 172201) of Universiti Malaysia Pahang
Publication Title
Nanoscale Advances
Volume
1
Issue
10
Publisher
Royal Society of Chemistry