Lead corrosion and formation of lead oxides from a lead-air cell in methanesulfonic acid
Document Type
Article
Publication Date
1-1-2016
Abstract
The corrosion of lead in methanesulfonic acid solution in the presence of a MnO2 air cathode in a primary lead-air cell is investigated. The highest power density of the lead-air cell is 2.8 mW cm-2. X-ray photoelectron spectroscopy and powder X-ray diffraction results demonstrate the formation of lead (II) oxide and lead (IV) dioxide on the air cathode after continuous discharge. Field emission scanning electron microscopy image shows that the surface coverage of lead (II) oxide and lead (IV) dioxide on the air cathode is only partial and will allow oxygen reduction.
Keywords
Anodic dissolution, Lead oxides, Lead-air cell, X-ray photoelectron spectroscopy
Divisions
Science
Publication Title
Journal of New Materials for Electrochemical Systems
Volume
19
Issue
4
Publisher
Ecole Polytechnique de Montreal