Structural, electrochemical, and adsorption studies of Ni and Zn benzylimidazole coordination polymers with terephthalate linkers
Document Type
Article
Publication Date
1-1-2018
Abstract
Two coordination polymers, [Ni(bim)2(L1)(H2O)2]n (CP-1) and [Zn(bim)(L1)(Cl)]n (CP-2) (bim = 1-benzylimidazole, L1 = terephthalic acid), were synthesized and characterized by physicochemical and spectroscopic methods. The Ni(II) center in CP-1 is octahedral, while the Zn(II) center in CP-2 is tetrahedral. CP-1 and CP-2 were used to modify carbon paste electrodes to assess their effect on the electrochemical behavior of ferricyanide. The redox reactions of ferricyanide on both electrodes proved to be reversible and diffusion controlled, with ferricyanide diffusion coefficients for CP-1 and CP-2 of 1.88 × 105 and 3.44 × 105 cm2 s−1, respectively. These coordination polymers were also investigated for their adsorption behavior toward two dyes: Chicago sky blue and methylene blue. CP-1 and CP-2 both rapidly adsorbed the anionic Chicago sky blue dye by different intermolecular interactions; in contrast, the cationic methylene blue dye was adsorbed to a lesser extent. The adsorption of these CPs depends on the charge but not the size of the dye. Addition of methanolic potassium nitrate solution caused the release of the adsorbed dyes.
Keywords
Adsorption, Aromatic compounds, Carbon, Dyes, Electrochemical electrodes, Electrodes, Nickel, Nickel compounds, Potash, Redox reactions, Spectroscopic analysis, Zinc, Zinc compounds
Divisions
CHEMISTRY
Funders
Financial support from University Malaya of Research Grant (RP011B-14SUS), IPPP grant (PG116-2014B), Fundamental Research Grant Scheme, FRGS (FP005-2015A),Higher Education Commission of Pakistan under FDP
Publication Title
Transition Metal Chemistry
Volume
43
Issue
1
Publisher
Springer Verlag