Nitrogen-doped graphene-supported zinc sulfide nanorods as efficient Pt-free for visible-light photocatalytic hydrogen production

Document Type

Article

Publication Date

1-1-2018

Abstract

Nitrogen-doped graphene-ZnS composite (NG-ZnS) was synthesized by thermal treatment of graphene-ZnS composite (G-ZnS) in NH3 medium. In the second step, the as-synthesized samples were deposited on indium tin oxide glass (ITO) by electrophoretic deposition for photocatalytic hydrogen evolution reaction. The as-prepared NG-ZnS-modified ITO electrode displayed excellent photocatalytic activity, rapid transient photocurrent response, superior stability and high recyclability compared to the pure ZnS and G-ZnS-modified ITO electrode due to the synergy between the photocatalytic activity of ZnS nanorods and the large surface area and high conductivity of N-graphene.

Keywords

Zinc sulfide, Nitrogen doped graphene, Hydrogen evolution, Photocurrent response, Synergistic effect

Divisions

CHEMISTRY,PHYSICS

Funders

Frontier Research Grant ( FG030-17AFR ),University of Malaya Centre for Ionic Liquids (UMCiL),Fundamental Research Grant Scheme (FRGS) FP011-2015A and FP039-2016A

Publication Title

International Journal of Hydrogen Energy

Volume

43

Issue

32

Publisher

Elsevier

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