trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis

Document Type

Article

Publication Date

1-1-2017

Abstract

The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C - H⋯F, C - H⋯Cl and C - H⋯π interactions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface.

Keywords

Crystal structure, Organotin, C—H...F inter­actions, Hirshfeld surface analysis

Divisions

CHEMISTRY

Funders

Sunway University (award No. INT-RRO-2017-096),University of Malaya (award Nos. RP017A-2014AFR, PG239-2016\#65532;A),Ministry of Higher Education, Malaysia (MOHE) Fundamental Research Grant Scheme (award No. FP033-2014B)

Publication Title

Acta Crystallographica Section E: Crystallographic Communications

Volume

73

Issue

5

Publisher

International Union of Crystallography

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