Enhanced marine antifouling performance of silver-titania nanotube composites from hydrothermal processing

Document Type

Article

Publication Date

1-1-2017

Abstract

Marine fouling is an age-old problem which continues to plague the maritime industry. The fouling process progresses from an initial formation of bacterial biofilm on unprotected surfaces. Silver is a well-known antimicrobial agent which is well-tolerated by mammals, while titania nanotubes have enhanced properties due to a greater specific surface area on the inner and outer surfaces of the tubular structure. A novel 2-step hydrothermal synthesis of a silver-titania nanotube (Ag/TNT) composite material is presented. The morphology, particle size, chemical content, crystal structure, optical properties and surface area were systematically characterized. Determination of biofilm inhibitory properties revealed that Ag/TNT with the lowest silver content (0.95 wt% Ag) decorated with Ag nanoparticles of ca. 3 nm reduced biofilm formation of marine bacterium Halomonas pacifica by 98% compared to pure titania nanotubes and bulk silver alone. Growth inhibition of marine microalgae Dunaliella tertiolecta and Isochrysis sp. were also observed.

Keywords

TiO2 nanotubes, Ag nanocomposite, Marine antifouling, Biofilm inhibitor, Halomonas pacifica

Divisions

PHYSICS

Funders

Ministry of Science, Technology & Innovation (MOSTI) of Malaysia: the Science fund program (04-02-12-SF0149), the National Nanotechnology Program Grant (NND/NA/(1)/TD11-002), HIR-Chancellery (UM.C/625/1/HIR/079), (J-21002-73810) and HIR-MOHE (UM.C/625/1/H

Publication Title

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volume

520

Publisher

Elsevier

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