Document Type
Article
Publication Date
1-1-2011
Abstract
In the title complex, [Cd-2(NCS)(4)(C13H19N3O)(2)], the two Cd-II ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N',N ''-tridentate Schiff base ligand complete a distorted CdN5S octahedral geometry about each Cd-II atom. In the crystal, the Schiff base aromatic rings of adjacent molecules are arranged above each other into infinite chains along the a axis with alternate centroid-centroid separations of 3.5299 (13) and 3.7857 (13) angstrom.
Keywords
Ligands
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
67
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA