Document Type
Article
Publication Date
1-1-2011
Abstract
The Pd-II ion in the title compound, [Pd(C17H14N3S2)(2)]center dot 2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)degrees. The indole NH groups are bonded to the pyridine solvent molecules via an N-H center dot center dot center dot N interaction. The crystal structure is consolidated by intermolecular C-H center dot center dot center dot S interactions.
Keywords
Key indicators: single-crystal X-ray study, T = 100 K, mean � (C–C) = 0.005 A ̊, R factor = 0.039, wR factor = 0.070, data-to-parameter ratio = 14.8
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
E67
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA