(Z)-5-Benzenecarbothioyl-1,11-dimethyl-6-phenyl-5H-dibenzo[d,f][1,3]diazepine
Document Type
Article
Publication Date
1-1-2011
Abstract
The sevenmembered ring in the title compound, C28H 22N2S, has a twocoordinate N atom as well as a threecoordinate N atom. The ring adopts a boatshaped conformation with two C atoms of one methylphenyl ring as the stern and the threecoordinate N atom as the prow. The N,N-dimethylethanethioamide fragment is nearly planar (r.m.s. deviation = 0.049 Å); the phenyl ring of the benzenecarbothioyl unit connected to the threecoordinate N atom is aligned at 83.72 (4)° with respect to the mean plane of this fragment. Weak intermolecular C -H⋯S hydrogen bonding is present in the crystal structure.
Keywords
Crystal structure, Hydrogen bonds, Ref F
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
67
Issue
2
Publisher
International Union of Crystallography