Document Type
Article
Publication Date
1-1-2011
Abstract
In the title complex, [Co(NCS)(2)(C13H19N3O)(H2O)], the Co-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds occur. In the crystal, intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot S, C-H center dot center dot center dot S and S center dot center dot center dot S [3.5546 (18) angstrom] interactions result in an infinite three-dimensional network.
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA