Document Type
Article
Publication Date
1-1-2011
Abstract
In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular pi-pi interaction occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) angstrom.
Keywords
Single-crystal X-ray study, T = 100 K, mean � (C–C) = 0.002 Å, R factor = 0.023, wR factor = 0.061, data-to-parameter ratio = 18.4
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
67
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA