Fabrication and characterisation of chitosan/poly vinyl alcohol nanofibres via electrospinning
Document Type
Article
Publication Date
1-1-2014
Abstract
In this study, chitosan nanofibres were fabricated using electrospinning process. Initially, chitosan powders were further deacetylated with sodium hydroxide to deprotonate the polymer chains and decrease the molecular weight. Subsequently, the treated chitosan (5 wt-% in 90:10 acetic acid/water ratio) were mixed with poly vinyl alcohol (8 wt-% in water) at different ratios in order to facilitate the electrospinning through cross-links formation. Field-emission scanning electron microscopic images showed that 60:40 (chitosan/poly vinyl alcohol) ratio was the threshold for formation of beads (chitosan/poly vinyl alcohol >50:50 contains imperfections) and that increasing chitosan/poly vinyl alcohol ratio from 20:80 to 60:40 decreased the average diameter of fibres from 80 to 40 nm. Fourier transform infrared spectra proved the formation of chitosan/poly vinyl alcohol cross-linked nanofibres.
Keywords
Chitosan, Poly vinyl alcohol, Nanofibres, Electrospinning, Deacetylation, Viscometry
Publication Title
Materials Research Innovations
Volume
18
Issue
S6
Publisher
Maney Publishing
Publisher Location
STE 1C, JOSEPHS WELL, HANOVER WALK, LEEDS LS3 1AB, W YORKS, ENGLAND