Effect of synthetic antioxidants on storage stability of calophyllum inophyllum biodiesel
Document Type
Article
Publication Date
1-1-2014
Abstract
Biofuels, especially biodiesels derived from renewable sources, are becoming increasingly important because of environmental and energy concerns. However, biodiesels composed of long chain unsaturated fatty acid esters are prone to oxidation. One such biodiesel is non-edible high acid value Calophyllum inophyllum oil-based biodiesel produced through a two-stage esterification process and one-stage transesterification process. In this study, the oxidation stability of biodiesel treated with three prominent antioxidants, namely pyrogallol, propyl gallate and tert-butylhydroxyquinone was evaluated. The induction period of biodiesel with or without antioxidant was measured according to the EN14112 standard using a Rancimat instrument. Antioxidants were added at 500 ppm, which in general improved the induction period. The samples were kept for 70 days and different properties that change during storage, namely induction period, density and kinematic viscosity were monitored. For all samples, oxidation stability decreased and kinematic viscosity increased because of the formation of oxidation products. Pyrogallol showed the best effect in retaining oxidation stability of Calophyllum inophyllum biodiesel.
Keywords
Storage stability, Biodiesel, Antioxidants, Calophyllum inophyllum
Divisions
fac_eng
Publication Title
Materials Research Innovations
Volume
18
Issue
S6
Publisher
Taylor & Francis
Publisher Location
STE 1C, JOSEPHS WELL, HANOVER WALK, LEEDS LS3 1AB, W YORKS, ENGLAND