The effect of bismuth on the structure and mechanical properties of GeO2-PbO-Bi2O3 ternary bulk glass system
Document Type
Article
Publication Date
1-1-2012
Abstract
This paper reports the elastic properties and structure of GeO2-PbO-Bi2O3 ternary bulk glasses which were successfully prepared by melt quenching technique. The study was performed by ultrasonic measurements and Fourier transform infra red (FTIR) spectroscopy. Increasing values of density, ultrasonic velocity and elastic moduli were observed due to substitution of bismuth to lead atoms with fixed composition of GeO2. Also, FTIR spectrum showed different profiles between samples with higher content of lead or bismuth. In Pb-rich samples all of the components contributed in the structure as network former; however, in Bi-rich samples lead and bismuth showed modifier behavior and the structure was depolymerized by adding of bismuth content. (C) 2012 The Ceramic Society of Japan. All rights reserved.
Keywords
Germanate glass bi2o3 pbo elastic properties ftir spectroscopy inorganic oxide glasses optical-properties elastic-constants vitreous system pressure moduli raman
Divisions
fac_eng
Publication Title
Journal of the Ceramic Society of Japan
Volume
120
Issue
1403
Additional Information
Bahari, Hamidreza Abd Aziz, Sidek Hj Kamari, Halimah Mohamed Yunus, Wan Mahmood Mat Adikan, Faisal Rafiq Mahamd