Determination of diffusion coefficients of selected long chain hydrocarbons using reversed- flow gas chromatographic technique
Document Type
Article
Publication Date
1-1-2011
Abstract
The reversed-flow gas chromatography (RF-GC) technique was used to study the evaporation rate and estimating the diffusion coefficient of samples. The RF-GC system comprises of six-port valve, sampling and diffusion column, detector and modified commercial gas chromatography machine. Selected long chain of hydrocarbons (99.99% purity) was used as samples. The solute (stationary phase) were carried out by carrier gas (mobile phase) to the detector. The data obtained from the RF-GC analysis were analysed by deriving the elution curve of the sample peaks using mathematical expression to find the diffusion coefficients values of respective liquids. The values obtained were compared with theoretical values to ensure the accuracy of readings. The interesting findings of the research showed the theoretical values of equilibrium at liquid-gas interphase lead to profound an agreement with the experimental evidence, which contributes for the references of future studies. © Copyright E-Journal of Chemistry 2004-2011.
Keywords
Diffusion coefficient, Liquid pollutants, Long chain hydrocarbons, RF-GC
Divisions
CHEMISTRY
Publication Title
E-Journal of Chemistry
Volume
8
Issue
4
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA