Chitosan-PEO proton conducting polymer electrolyte membrane doped with NH 4NO 3

Document Type

Article

Publication Date

1-1-2011

Abstract

The polymer electrolyte membrane in this work was prepared using the solution casting technique. The polymer host is a blend of chitosan and polyethylene oxide. The solution of the blend was added with ammonium nitrate (NH 4NO 3) to supply the charge carriers for ionic conduction. From X-ray diffraction and scanning electron microscopy image, it can be inferred that the film of the 3 : 2 chitosan-polyethylene oxide blend is the most amorphous and suitable to serve as polymer host. The sample containing 40 wt-%NH 4NO 3 exhibited the highest room temperature conductivity of 1.02×10 -4 S cm -1. The salted samples were also characterised using X-ray diffraction and scanning electron microscopy in order to establish conductivity variation with different salt contents. © W. S. Maney & Son Ltd. 2011.

Keywords

Chitosan-PEO blend, Conductivity, Proton conducting polymer electrolyte, SEM, XRD, Ammonium nitrate, Conductivity variation, Polymer electrolyte membranes, Proton-conducting polymer electrolytes, Room-temperature conductivity, Salt content, Scanning electron microscopy image, Solution-casting technique, Ammonium compounds, Amorphous films, Conducting polymers, Electric conductivity, Polyelectrolytes, Polyethylene oxides, Polyethylenes, Protons, Scanning electron microscopy, Thermoplastics, X ray diffraction, Chitosan

Divisions

PHYSICS

Publication Title

Materials Research Innovations

Volume

15

Issue

2

Publisher

Springer Verlag (Germany)

Additional Information

Department of Physics, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA

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