1-Methyl-3,3-bis­[(4-methyl­phen­yl)sulfan­yl]piperidin-2-one

Document Type

Article

Publication Date

1-1-2011

Abstract

The piperidone ring in the title compound, C 20H 23NOS 2, has a half-chair distorted to a twisted-boat conformation [Q T = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.28 (5) and 46.41 (5) Å, respectively]. In the crystal, the presence of C-H⋯O and C-H⋯π interactions leads to the formation of supramolecular layers in the ab plane.

Keywords

data-to-parameter ratio = 16.9, mean σ(C-C) = 0.002 Å, R factor = 0.039, single-crystal X-ray study, T = 100 K, wR factor = 0.107

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

67

Issue

10

Publisher

International Union of Crystallography

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