Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
Document Type
Article
Publication Date
1-1-2011
Abstract
The polymeric title compound, [Ce(C7H3N 2O6)3(C2H6OS) 2] n, exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol-ecules are disordered in a 0.926 (3):0.074 (3) ratio.
Keywords
Ligands, Crystal structure, X-ray diffraction
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
67
Issue
6
Publisher
International Union of Crystallography
COinS